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Physical Chemistry-II
Week 12: Translational, rotational, vibrational and electronic partition function and their comparison
Week 12: Translational, rotational, vibrational and electronic partition function and their comparison
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Course Material
Week 1: Introduction to quantum mechanics, Schrodinger’s wave equation
Week 2: Postulates of quantum theory
Week 3: Operators
Week 4: Eigen value, Eigen function
Week 5: Orthogonality and normalized wave functions
Week 6: Motion of particle in three dimensional box and idea of degeneracy
Week 7: Mathematical treatment of rigid rotator and calculation of bond length of simple molecule
Week 8: Mid Term Exam
Week 9: Stirling approximation. Probability. Statistical treatment of entropy. The Boltzman distribution law
WEEK 10: Partition function. Physical significance of partition function. Separation of partition function
Week 11: Partition function and thermodynamics functions live internal energy and entropy.
Week 12: Translational, rotational, vibrational and electronic partition function and their comparison
Week 13: Concept of conductance of electrolytes. Debye–Huckle equation and limiting law. Ionic strength, weak electrolytes and Debye–Huckle theory.
Week 14: Activity and activity coefficients of electrolytic solutions. Determination of activities.
Week 15: Concentration cells. Determination of e.m.f. of concentration cells with and without transference. Fuel cells and hydrocarbon fuel cells
Week 16: Final Term Exam
Chapters
16
Department
Chemistry(SCB)
Teacher
Dr. Irfan Ullah