Theory: Organic Chemistry – I (Cr.03)
- Nomenclature of aliphatic, alicyclic, aromatic, heterocyclic organic compounds, concept of aromaticity.
- Conformational Isomerism in Acyclic Compounds, Cyclobutane, Cyclopentane, Cyclohexane, Mono substituted, Di-substituted Cyclohexanes and condensed rings. Geometrical Isomerism: E/Z Nomenclature, Cis/Trans & Syn/Anti Nomenclature, Determination of configuration. Optical Isomerism: Chirality and Symmetry. Optical isomerism of Compounds upto three Asymmetric Centers, Relative and Absolute configuration, R/S nomenclature, Racemization, Resolution of racemic mixture, Optical isomerism in biphenyls, allenes and spiro compounds, Asymmertric Synthesis, Stererospecificity and Stereoselectivity.
- The effect of structure & medium and steric effects on the strength of acids and bases and on acid-base equilibria. Resonance and inductive effects on acidity and basicity. Linear free energy relationships.
- Structure, methods of generation, reactions and synthetic applications of carbenes, nitrenes and arynes.
Organic Chemistry Lab. I (Cr.01)
Separation & Identification of two and three component mixture of organic compounds by physical and chemical methods.