CHEM– 464 Advanced Inorganic Chemistry (Cr.03)

INTRODUCTION & LEARNING OUTCOMES:

Stereochemistry Periodicity:

Concepts of Stereochemistry and Periodicity (Periodic Properties), Introduction, First and Second row anomalies, the use of d-orbitals by nonmetals, Reactivity and d-orbital participation, The use of p-orbitals in pi-bonding, Periodic anomalies of non-metals and post transition metals.

Nuclear Chemistry:

Introduction, classification of Nuclides, Radioactivity and radioactivite series, artificial radioactivity, units of radioactivity, Determination of Half-life, Nuclear Fission and Fusion reactions, Applications of radio Isotopes as traces

 Structure of Inorganic Solids:

Introduction, The close packing of spheres, the structure of ionic solids, Ionic radii, Crystal structures and defect solid state. Thermal Methods of analysis: Introduction, instrumentation, applications.

Thermal methods of analysis :introduction,instrumentation and application

Attitude
Develop an attitude of creativity, as demonstrated by students possessing a strong sense of curiosity, asking questions actively, challenging assumptions or engaging in inquiry together with teachers.
Ability
Develop the ability/skill needed to discover/innovate/create, as demonstrated by students possessing
critical thinking skills to assess ideas, acquiring research skills, synthesizing knowledge across disciplines
or applying academic knowledge to self-life problems and the application of chemistry in daily life.

Inorganic Chemistry Lab. III (Cr.01)

Use of some organic reagents for the estimation of various elements a) 8–Hydroxyquinoline Al (III) and Fe (III) b) Nitron (NO3 -1 ) c) Salicyladoxine Ni (II) in presence of Cu (II) d) Anthranilic Acid Co (II) and Zn (II) e) Pyrogallol Bi3+ a)

Chromatographic Techniques - Column, Thin layer and Paper chromatographic techniques for the qualitative separation of inorganic compounds

b) Applications of Solvent extraction and ion exchange techniques

Synthesis of following Inorganic compounds / Complexes in a pure state and determine their state of purity a. [Co(NH3)5Cl]Cl 30 b. [Co(NH3)5NO2]Cl2 c. [Co(NH3)5 d. ONO]Cl e. [Co(en)3]Cl3

Text books to be used for the course

1. Huheey, J. E., Keiter, E. A. and Keiter, R. L., “Inorganic Chemistry: Principles of Structure and Reactivity”, 4th Ed., Harper and Row, New York, (2001). 2. Cotton, F. A., Wilkinson, G. and Gaus, P. L., “Basic Inorganic Chemistry”, 3rd Ed., Wiley, New York, (1995). 3. Atkins, P. and Jones, L., “Chemicals Principles” Freeman & Co., NY (2002). 4. Cotton, F.A., Wilkinson, G., Murillo C.A. and Bochmann, M. “Advanced Inorganic Chemistry”, 6th Ed., Wiley-Intersceince, New York, (1999). 5. Bassette, J., Denney, R.C. Jefery, G.H. and Mendham, J. “Vogel‟s Textbook of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis”. 4 th Edition, English Language Book Society, UK (1981). 6. Vogel, A.I., “A Textbook of Micro and Semi-micro Qualitative Inorganic Analysis” Longman Green & Co. NY (1995).

Description of system of Evaluation (Exam, assignments etc)

• Attendance    ( Minimum attendance 75% is necessary to appear in the examination)
• behaviour      
• Assignment & presentation
• Sessional                  15%   (Based on attendance,behaviour and assignment and presentations)
• Mid Term Exam          15%
• Project/Practical work: 25%
• Final exam:                 45%

  Key dates and time of class meetings

• Semester Start : 12 october  2020
• time table 

1. Monday  11-12 A.M
2. Tuesday 11-12 A.M
3. Wednesday 11-12 A.M
4. Thursday (lab) 11-12 A.M

 Weekly lectures plan