Inorganic CHEM 363

 

             DEPARTMENT OF CHEMISTRY

              Weekly Distribution of Syllabus

Inorganic Chemistry 2 BS-6 CHEM-363 (Cr.03+01)

COURSE OUTLINE  SPRING 2020

Course Tittle: Inorganic Chemistry-II

Course Code: CHEM- 363, SS, Regular, Exppp-z

Credit Hours: 3+1

Instructor: Dr. Abdul Karim

Email: [email protected]

COURSE OUTLINE SPRING 2020

Course Tittle: Inorganic Chemistry II

Course Code: CHEM- 363

Credit Hours: 3+1

Instructor: Dr. Abdul Karim

Email: [email protected]

DESCRIPTION & OBJECTIVES

For teaching all science subjects, transmission, transaction and transformation mode of learning have prime importance to prepare the marketed oriented students. The brief description of this course is,

  1. The course is related to synthesis of different metal carbonyls complexes  
  2. Classification of Carbonyls
  3. Synthesis of transition metal carbonyls complexes which are extensively used in industrial and laboratory processes to catalyze different chemical reactions.
  4. Here we will study different types of bonds in the molecules such as Pi- bonds, metallic bonds, bridge bonds and different types of forces exist among the molecules.  
  5. Chelates and effects of chelates
  6. Types of reagents and their applications in different fields of chemistry

BOOKS RECOMMENDED FOR READINGS

  1. Greenwood, N.N and Easnshaw, A. Chemistry of the elements 2nd ED. Pergaman, N.Y 1984.
  1. Joly, W.L. Principles of Inorganic Chemistry, McGraw Hill, NY 1985.
  1. Sharpe A.G Inorganic Chemistry 2nd Ed. John Wiley, NY 1987.
  2. Inorganic Chemistry, J.E. Huheey 3rd Edn. 13. Topics in Current Chemistry    (Inorganic/Bio-Chemistry), Vol. 64 14.
  3. A Text Book of Quantitative Inorganic Analysis- A.I. Vogel
  1. De Lavis, R., Principles of Quantitative Chemical Analysis 1st Ed. WCB McGraw Hill ,

NY 1997.
  1. Kotz, J. C. and Treichel , P. Chemistry and Chemical reactivity 4th Ed. Saunders College  Publishing N.Y. 1999.
  1. Cotton F.A. and G. Wilkinson Advanced Inorganic Chemistry 5th Ed. John Wiley NY 1998.

 

Introduction:

The Inorganic Chemistry has developed remarkably in last few decades. Its history chemistry is reflected from its unexpected discoveries. There are so many salts, reagents, catalysts, Pharmaceutical products which are prepared by the individual and combine effort of both Inorganic and organic researchers Synthesis of organoaluminium compounds, Nickle tetracarbonyl by Mond, synthesis of Grignard Reagent, Synthesis of organoplatinum compounds used for treatment of cancer, Synthesis of dialkylzinc, discovery of Fischer tropsch process, Reppe process, Mond process etc. are some of its important discoveries which indicates its process of development. Number of research articles relating to the structure of different coordination compounds are reporting rapidly in International Journals. Now there are many Journals which are specifically dealing with the inorganic metal Chemistry. One important Journal, International Journal of Inorganic chemistry, is publishing hundreds of research papers annually. Some other Journals have been launched by American Chemical society relating to coordination chemistry.

The organotransition metal compounds are fun to study and useful in many respects. Many interesting discoveries   and useful applications are expected in future. Due to unexpected behavior of organotransition metals complexes, their study is very interesting and their chemistry is full of varieties.

CONTENTS

  1. Bonding Model for Nontransition metals

VESPR model followed by VB Theory for determination of Geometry of molecules and ions containing sigma bonds as well as pi bonds, band Theory of metallic bonding(Conductors, Insulators and Semiconductors), Bonding in electron deficient compounds, hydrogen bondings.

  1. Pi-Acceptor ligands

Valuation of structure based on spectroscopic evidence, chemistry of metal carbonyls, Application of metal carbonyls and their derivatives to catalysis and organic synthesis

  1. Organic Reagents used in inorganic analysis

Types of reagents, their specific nature and method of applications with specific examples, complexometric titration involving various reagents( EDTA etc.),Chelates and chelating effect, Role of organic reagents in different analytical techniques.

 

COURSE SCHEDULE

Weeks

Topics and Readings  

   1.

 Introduction of Dipole moment its  measurement and implications in inorganic molecules

   2.

 Classification of intermolecular  forces, their mode of development

   3.

Explanation of Dipole dipole forces , Dipole induced dipole forces,  London dispersion forces

   4.

Hydrogen bonding, mechanism, types with examples.

   5.

Bond theory of metallic bonding  

   6.

Introduction to EAN rules as applies to metal carbonyls, Evaluation of structures based on spectroscopic evidences

   7.

Classification of transition metal Carbonyls   

   8.

Preparation of mononuclear carbonyls such as Ni(CO)4, Cr(CO)6,Mo(CO)6,W(CO)6,

   9.

Mid Examination

   10.

Binuclear metal carbonyls : Fe2(CO)10 , Co2(CO)8, Mn2(CO)10 (Str. Preparation and reactions  of poly nuclear metal carbonyls : Fe3(CO)12 ,Co4(CO)12 ,Ir4(CO)12 (Str. Preparation  and reactions 

   11.

Chemistry of Metal Carbonyls

   12.

Applications of Metal Carbonyls and their derivatives to catalysis and organic synthesis

   13.

Types of reagents , their specific nature and methods of applications with examples, and their role in different types of chemistry

   14.

Complexometric titrations involving various reagents (EDTA etc )

   15.

Chelates and chelate effect

   16.

Revision of some important topics
 

 

ASSESSMENT CRITERIA

 A: Sessional

The assessment based on Presenation Participation  and Attendance

           B: Mid: 15

C: Final exam: 45

D: Practical: 25

RULES AND REGULATIONS

  1. Attendance
  2. Regular students will be appreciated in the class

Course Material

Other Courses by Dr. Abdul Karim