SPRING 2020

 

Course Tittle:                          Physical Chemistry-II 

Class:                                       M. Sc (Regular)

Sesson:                                    2019-2021

Course Code:                          CHEM-571

Credit Hours:                          03+01

Instructor:                               DR. MUHAMMAD AMIN

Email:                                      [email protected]

DESCRIPTION& OBJECTIVES

Physical chemistry-II is designed for the students of M.Sc II semester and BS-VI semester in order to teach the students the detailed objectives, theory, mathematical calculations of three major and most important  fields of Physical chemistry like Quantum mechanics, Statistical mechanics and Electrochemistry.  It enables the students to apply the concepts of Quantum treatment on very simple and some of the complex molecules. Quantum chemistry is a very powerful tool for  studying  the properties of molecules and their reactions taking place between the molecules. The recent years’ development in quantum chemistry methods, especially in theoretical methods has made it possible for quantum chemistry calculations to reach accuracies comparable to those obtained in experiments for molecules of moderate sizes. This is further facilitated by the rapid development of computer technologies that has greatly encouraged the chemists to use quantum chemistry to understand, simulate model, and predict molecular properties and their reactions, properties of nanometer materials, and reactions and processes taking place in biological systems. While doing so the Statistical mechanics plays the role of a bridge between the two concepts.

READINGS

  1. Julio Atkins, Peter &Depaula “Atkin’s Physical Chemistry”2nd Edition, Oxford University Press, England (2009).
  2. Gurdeep Raj. “Advanced Physical Chemistry” Krishna Prakashan Media (P) Ltd. New Delhi (2010).
  3. Haq Nawaqz  Bhatti, “ Modren Physical Chemistry”, Carvan Book House Lahore (2019).
  4. A.S Negi, S. Chand. “A text Book of Physical Chemistry” New Age International, (2007).
  5. Barrow G.M. "PHYSICAL CHEMISTRY" 5TH Ed. McGraw Hill, Inc. CA 1998
  6. Castellan G.W."PHYSICAL CHEMISTRY"3RD Ed. Norasa publishing house DEHLI 2004
  7. Alberty R. and Silvey, A. "physical chemistry" 7th Ed. John Wiley and sons NY 1992
  8. Gurdeep R. "Advanced physical chemistry "3rd Ed. DEHLI 2008

 

 

COURSE SCHEDULE

 

 

Topics and Readings

Dates

1.

Postulates of Quantum theory , Operators , Eigen value

 

March 2-4, 2020

2.

Eigen function , orthogonality and normalized wave function

 

March 9-11, 2020

3.

Motion of particle in three dimensional box and idea of degeneracy

 

March 16-18, 2020

4.

Solution of Hydrogen atom

 

March 24-25, 2020

5.

Solution of Hydrogen atom and calculation of Quantum Numbers

 

April 6-8, 2020

 

Physical function of partition functions ,Separation of partition function

 

April 13-15, 2020

April 20-22, 2020

 

Mid Term Examination

April 27- May 01, 22, 2020

 

Stirling approximation , Probability ,Statistical treatment of entropy

 

May 4-6, 2020

6.

The Boltzman distribution law and partition function

 

May 11-13, 2020

7.

Physical function of partition functions ,Separation of partition function

 

May 18-20, 2020

09

Partition function and thermodynamic functions

 

May 25-27, 2020

10

Internal energy and Entropy

 

June 1-3, 2020

11

Translational rotational vibrational and electronic partition function and their comparison

 

May 4-6, 2020

12

concept of conductance of electrolytes

 

May 11-13, 2020

13

Debye-Huckle equation and limiting law

 

May 18-20, 2020

14

Ionic strength , weak electrolyte and Debye Huckle theory

 

May 25-27, 2020

15

Activity and activity coefficients of electrolytic solutions , determination of activities

 

June 8-10, 2020

 

16

Determination of e.m.f of concentration cells ,Fuel cell and hydrocarbon fuel cell

 

June 15-17, 2020

17

Final Exams

June 22-26, 2020

 

RESEARCH PROJECT

Students are allotted with the assignments and presentations keeping in view the importance of the topic already studied. The emphasis is made on the practical applications 0f the course topic studied. In practical/ lab assignments, the handling of different instruments and the basic training is given to the students in friendly environment.

ASSESSMENT CRITERIA

Sessional: 15

Mid Term: 15

Practical Exam: 25

Final exam: 45

RULES AND REGULATIONS

  1. Class attendance (75%)in necessary for all students
  2. During paper, mobile phone is not allowed.
  3. Strict invigilation are observed during the exams

Course Material